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    • 专利摘要:
    method of producing non-oriented electric steel sheet. The present invention relates to an unoriented electric steel sheet having a high magnetic flux density in a steel plate rolling direction which is produced by hot rolling a crude steel material comprising c: no more than 0.03 mass%, si: not more than 4 mass%, mn: 0.03 ~ 3 mass%, al: not more than 3 mass%, s: not more than 0.005 mass% n: not more than 0.005% by mass and the equilibrium being fe and inevitable impurities, and then cold rolling and final annealing to produce a non-oriented electric steel sheet, characterized in that a crystal grain size before Cold rolling is provided in no more than 100 mm and the final annealing is conducted by rapidly heating to a temperature exceeding the recrystallization temperature at an average temperature elevation rate of not less than 100 ° c / s.
    公开号:BR112013015464B1
    申请号:R112013015464-0
    申请日:2011-12-16
    公开日:2019-03-26
    发明作者:Yoshiaki Zaizen；Yoshihiko Oda；Hiroaki Toda
    申请人:Jfe Steel Corporation；
    IPC主号:
    专利说明:

    Descriptive Report of the Invention Patent for METHOD OF PRODUCING ELECTRIC STEEL SHEET NOT ORIENTED.
    TECHNICAL FIELD [001] The present invention relates to a method of producing an unoriented electric steel sheet, and more particularly to a method of producing an unoriented electric steel sheet having excellent magnetic properties in its rolling direction. RELATED TECHNIQUE [002] In the global trends of saving energy in consideration of protecting the global environment, this is recently and strongly demanded to provide electrical equipment at a higher efficiency and a smaller scale for the purpose of saving energy even in the field of electrical equipment. In non-oriented electrical steel sheets widely used as a core material in electrical equipment, therefore, it is strongly desired to improve the magnetic properties or to make a high magnetic flux density and a low iron loss.
    [003] Up to now, in electrical steel sheets not oriented, it is sought to make the magnetic flux density high by appropriately selecting a type of connection element (s) to be added and composing the size of the crystal grain before cold rolling as much as possible and still optimizing a reduction in rolling in cold rolling, although it is sought to make the loss of iron low by adding an element to enhance the specific strength or by reducing the thickness of the sheet to thereby improve magnetic properties.
    [004] In a starter or similar for hybrid cars, a segment core is adopted from the point of view of improving an efficiency in the production of an engine core from
    Petition 870180066007, of 7/31/2018, p. 8/37
    2/24 a steel plate. The segment core is a technique to improve the characteristics of the engine by dividing a core into multiple segments and puncturing a toothed portion of each segment in the direction of rolling of the steel sheet and then mounting them on a core instead of the that the entire core is punctured as a unit of a crude steel sheet as in conventional technique.
    [005] In the segment core, the longitudinal length of the toothed portion concentrating the magnetic flux is the rolling direction of the steel sheet, so that the magnetic properties in the rolling direction of an electric steel sheet as a raw material make it become very important. As a material having excellent magnetic properties in the rolling direction, an electrical grain oriented steel sheet having a Goss orientation aligned in the rolling direction is mentioned. However, this is high in the cost of production because a secondary recrystallization process is necessary, so that it is difficult to adopt it in the segment core. Therefore, the non-oriented electric steel sheet is considered to be an ideal material for the segment core if the magnetic flux in the rolling direction can be enhanced.
    [006] As a suitable material for such a segment core, for example, Patent Document 1 and Patent Document 2 disclose a method in which excellent magnetic properties are obtained in a lamination direction in the plane and a vertical direction thickening the crystal grain size after hot coil annealing and controlling a reduction in lamination in cold rolling.
    PREVIOUS TECHNICAL DOCUMENTS
    PATENT DOCUMENTS [007] Patent Document 1: JP-A-2004-332042 [008] Patent Document 2: JP-A-2008-127600
    Petition 870180066007, of 7/31/2018, p. 9/37
    3/24
    SUMMARY OF THE INVENTION
    TASK TO BE SOLVED BY THE INVENTION [009] In the method of Patent Document 1, however, it is necessary to reduce steel impurities to an ultra-low volume as well as to make the temperature of a hot coil annealing high to provide a grain size of crystal before cold rolling in no less than 300 μπι, and consequently there is a problem in productivity and cost. Also, in the technique of Patent Document 2, it is necessary to thicken the crystal grains in the hot coil annealing, so that there is a problem in the production cost.
    [0010] The invention is made by virtue of considering the problems above conventional techniques and an inexpensive method of producing a non-oriented electric steel sheet having excellent magnetic properties in the direction of rolling of the steel sheet must be proposed, concretely having a high magnetic flux density. SOLUTION TO THE TASK [0011] The inventors have done several studies in order to solve the above problems. As a result, it has recently been discovered that the magnetic properties in the lamination direction are considerably improved by providing a crystal grain size before cold rolling at no more than 100 μπι and composing a temperature rise rate at the final annealing faster than that conventional in a method of producing an electric steel sheet not oriented by hot rolling, cold rolling and final annealing in the same way as the conventional method, and the invention has been accomplished.
    [0012] That is, the invention is a method of producing an electrical steel sheet not oriented by hot rolling of a crude steel material comprising C: no more than 0.03% by weight, Si: no
    Petition 870180066007, of 7/31/2018, p. 10/37
    4/24 more than 4% by mass, Mn: 0.03 ~ 3% by mass, Al: no more than 3% by mass, S: no more than 0.005% by mass, N: no more than 0.005% by mass and the balance being Fe and unavoidable impurities, and then cold rolling and final annealing to produce a non-oriented electric steel plate, characterized in that a crystal grain size before cold rolling is provided in no more than 100 μΐη and the final annealing is conducted by rapidly heating to a temperature exceeding the recrystallization temperature at an average temperature rise rate of not less than 100 ° C / s.
    [0013] The crude steel material in the production method of the invention is preferable to still contain one or two of Sn and Sb in an amount of 0.005-0.5% by weight, respectively, in addition to the above chemical composition.
    [0014] In the production method of the invention, it is also preferable that a decarburization annealing is carried out after rapid heating.
    EFFECT OF THE INVENTION [0015] According to the invention, electrical steel sheets without orientation having excellent magnetic properties in the rolling direction can be supplied inexpensively, so that they can be favorably used as a core material for the segment core, transformer core and the like.
    BRIEF DESCRIPTION OF THE DRAWINGS [0016] FIG. 1 is a graph showing an influence of a rate of temperature rise on final annealing on a magnetic flux density in a rolling direction.
    [0017] FIG. 2 is a graph showing an influence of the grain size and rate of temperature rise before cold rolling on a magnetic flux density in a rolling direction.
    Petition 870180066007, of 7/31/2018, p. 11/37
    5/24
    CARRYING OUT WAYS TO CARRY OUT THE INVENTION [0018] Initially, an experiment based on the development of the invention will be described below.
    [0019] A crude steel material (plate) with a chemical composition comprising C: 0.0025% by mass, Si: 3.3% by mass, Mn: 0.16% by mass, Al: 0.001% by mass, N: 0.0019% by mass and S: 0.0010% by mass is heated to 1100Ό for 30 minutes and hot rolled to form a hot rolled plate 2.0 mm thick, and then the hot rolled plate hot is subjected to hot coil annealing and a single cold rolling to form a cold rolled sheet having a final thickness of 0.35 mm. Thereafter, the cold-rolled sheet is subjected to final annealing by heating up to 740Ό in a direct current heating furnace while varying a rate of temperature rise within a range of 30 ~ 300Ό / 8, then heating up to 1000Ό at SOO / s, saturating in the temperature for 10 seconds and then cooling. A sample in the L direction of 180 mm long x 30 mm wide, where the rolling direction (L direction) is a longitudinal direction, is cut from the steel sheet after final annealing and subjected to a single plate magnetic test to measure a magnetic flux density B50 at a magnetizing force of 5000 A / m.
    [0020] In FIG. 1 the results of the above experiment are shown as a relationship between a rate of temperature rise and a magnetic flux density in the rolling direction, from which it is understood that electrical steel sheets having a high magnetic flux density in the direction of lamination are obtained by heating rapidly at a temperature rise rate of not less than 10000 / s to conduct the final annealing. This is considered due to the following fact.
    Petition 870180066007, of 7/31/2018, p. 12/37
    6/24 [0021] Primary recrystallization is a phenomenon caused by using displacement deformation work as a driving force. In general, a stored displacement energy introduced in cold rolling (deformation work) has a dependence on crystal orientation and satisfies {111}> {110}> {100}. In the case of heating at a low rate, therefore, orientation grains {111} having a high stored energy preferentially cause recrystallization through dependence on crystal orientation. However, in the case of rapid heating, the confinement of the crystal orientation dependence is released to cause recrystallization from another orientation, so that {110} or {100} orientation grains increase, and consequently the magnetic properties in the L direction. are considered to be improved.
    [0022] In the conventional method of producing non-oriented electric steel sheets, it is sought to suppress the occurrence of orientation grains {111} (hereinafter abbreviated to grains {111} or similar) and to improve the magnetic properties by conducting an annealing hot rolled coil at higher temperatures and making a crystal grain size before large cold rolling. In the case of rapid heating, however, the behavior of recrystallization changes a lot as mentioned above. Now, an influence of the crystal grain size before cold rolling on the magnetic properties (magnetic flux density in the rolling direction) is examined.
    [0023] A plate containing C: 0.0025% by weight, Si: 3.3% by weight, Mn: 0.15% by weight, Al: 0.001% by weight, N: 0.0022% by weight and S : 0.0013% by mass is heated to 1100Ό for 30 minutes and hot rolled to form a hot rolled sheet of 2.0 mm in thickness. Then, the hot-rolled sheet is subjected to
    Petition 870180066007, of 7/31/2018, p. 13/37
    7/24 a hot coil annealing under conditions so that the annealing temperature is varied within a range of 850-1100Ό and maintained for 30 seconds, whereby the crystal grain size is changed before lamination cold. Subsequently, the hot-rolled sheet is subjected to a single cold rolling to form a cold-rolled sheet having a final thickness of 0.35 mm and still a final annealing by heating up to 740Ό in a direct current heating furnace. at a temperature rise rate of 20Ό / 8 or SOOO / s, heating up to 1020Ό at SOO / s, saturating at this temperature for 10 seconds and then cooling. A sample in the L direction 180 mm long x 30 mm wide, where the rolling direction (L direction) is a longitudinal direction, is cut from the cold-rolled steel sheet after final annealing and subjected to a magnetic test single plate to measure a magnetic flux density B50 at a magnetizing force of 5000 A / m.
    [0024] In FIG. 2 the results of the above experiment are shown. As seen from FIG. 2, when rapid heating is carried out at SOOO / s, the magnetic flux density in the rolling direction is increased in such a region that the grain size before cold rolling is no more than 100 μπι, while when heating is performed at a low rate of 20Ό / 8, the magnetic flux density is inversely decreased. Although this reason is not clear at this point, it is considered as follows.
    [0025] When the hot coil annealing temperature is low and the crystal grain before cold rolling is small, grains {111} preferably grow on the recrystallization annealing after cold rolling. For this purpose, when the rate of temperature rise in the final annealing is slow as in the usual annealing, grains {111} are developed. However, when
    Petition 870180066007, of 7/31/2018, p. 14/37
    8/24 the rate of temperature rise is high as previously mentioned, the recrystallization of grains {111} is suppressed and grains {110} or grains {100} are relatively increased. In addition, grains {110} or grains {100} are preferably grown by invading grains {111} at subsequent saturation, whereby the magnetic properties in the lamination direction are improved.
    [0026] On the other hand, when the hot coil annealing temperature is high and the crystal grains before cold rolling are large, grains {110} or grains {100} are easily recrystallized by raising the elevation rate temperature as previously mentioned. However, since the grain size before cold rolling is large, the grain ratio {111} after recrystallization becomes small when compared to the case that the grain size is small, so it is considered that the ratio of grains {111} invaded by grains {110} or grains {100} becomes small in the subsequent saturation and grains {110} or grains {100} are not sufficiently developed and consequently the improvement of magnetic properties in the direction of lamination is not recognized.
    [0027] From the above experimental results, it can be seen that it is effective to provide the grain size before cold rolling in no more than 100 μπι and conduct heating on the final annealing by rapidly heating at the rate of temperature rise of not less than 10000 / s in order to improve the magnetic properties in the rolling direction. In addition, the term grain size used here means an average crystal grain size in an L section measured by linear analysis. The grain size before cold rolling is preferable to be no more than 90 μπι. [0028] The invention is developed based on the above knowledge.
    [0029] The chemical composition of the electric steel sheet does not
    Petition 870180066007, of 7/31/2018, p. 15/37
    Oriented 9/24 of the invention will be described below.
    [0030] C: no more than 0.03% by mass [0031] Solid-solute C in displacement of steel bars introduced in cold rolling and a deformation band is easily formed. The deformation band has an effect of preferably growing Goss orientation grains of {110} <001> on recrystallization during final annealing and improving the magnetic properties in the lamination direction. However, when the C content exceeds 0.03% by weight, there is a fear that decarburization will become insufficient as mentioned later, so that an upper limit on the C content in the crude steel material is 0.03% en masse in the invention.
    [0032] On the other hand, when C is present in an amount of not less than 0.005% by mass in one stage of a product, magnetic aging is caused to deteriorate the magnetic properties. Therefore, if the C content in the crude steel material exceeds 0.005% by weight, it is preferable that the C content in steel is reduced to no more than 0.005% by mass by decarburizing annealing before product formation. Decarburization annealing can be conducted at any time after rapid heating in the final annealing. Most preferably, the C content after decarburization is not more than 0.003% by weight. In addition, C is inevitably included, but may be 0% by weight in principle.
    [0033] Si: no more than 4% by mass [0034] Si is an element having the effect of increasing a specific strength of steel to reduce an iron loss. However, when it is added in an amount exceeding 4% by weight, steel is difficult to produce by rolling because it is hardened. Therefore, the upper limit of Si is 4% by mass. In addition, when the iron-loss property is enhanced, the addition of
    Petition 870180066007, of 7/31/2018, p. 16/37
    10/24 not less than 1.0% by mass is preferable.
    [0035] Mn: 0.03 ~ 3% by mass [0036] Mn is a necessary element to prevent hot fragility through S to improve hot machinability. However, the above effect is small in quantity of less than 0.03% by mass, while the addition exceeding 3% by mass saturates the above effect and causes the raw material cost to increase. Therefore, the Mn content is a range of 0.03 ~ 3% by weight.
    [0037] Al: no more than 3% by mass [0038] Al is an element having an effect of increasing a specific strength of steel to reduce an iron loss in the same way as Si. However, the addition exceeding 3% in mass deteriorates the lamination property, so the addition of 3% by mass is an upper limit. In addition, the effect of improving the magnetic flux density in the lamination direction according to the invention is considerably developed when the Al content is not more than 0.01% by mass, so that Al is preferable to be no more than 0.01% by weight when the effect of reducing iron loss through Al is not used. Although Al is inevitably included by adding it as a deoxidizing agent, it can be 0% by mass in principle.
    [0039] S: no more than 0.005% by mass, N: no more than 0.005% by mass [0040] S and N are incidental impurities decreasing the magnetic properties in the invention, so that each quantity is limited to no more than 0.005% by mass. Also, these elements can be 0% by mass in principle.
    [0041] The non-oriented electric steel sheet of the invention may contain Sn and Sb within the next range in addition to the above ingredients. [0042] Each of Sn and Sb: 0.005-0.5% by mass
    Petition 870180066007, of 7/31/2018, p. 17/37
    11/24 [0043] Sn and Sb are elements not only improving the texture to increase the density of magnetic flux, but also preventing oxidation or nitriding of the surface layer on the steel plate to suppress the formation of fine grains in the surface layer for that improve the magnetic properties. In order to develop such an effect, it is preferable to add one of Sn and Sb in an amount of not less than 0.005% by weight. On the other hand, when each Sn and Sb content exceeds 0.5% by mass, there is a fear of obstructing the growth of the crystal grain in the final annealing to deteriorate the magnetic properties. Therefore, each of Sn and Sb is preferable to be added within a range of 0.005-0.5% by mass.
    [0044] Furthermore, it is not refused that Sn and / or Sb of less than 0.005% by mass is included as an impurity.
    [0045] In the non-oriented electric steel plate of the invention, the balance except for the above ingredients is Fe and incidental impurities. However, the addition of an ingredient except those above is not rejected within a scope and does not impair the effect of the invention. As a harmful element, Ti, V, Nb and the like of no less than 0.003% by mass are exemplified. As a harmless element, P and the like of no more than 0.2% by weight are exemplified.
    [0046] Next, the production method of the non-oriented electric steel sheet of the invention will be described.
    [0047] The non-oriented electric steel sheet of the invention is produced by melting a steel having the chemical composition described above adapted to the invention through a commonly known refining process using a converter, an electric oven, a degassing apparatus a vacuum or the like, forming on a crude steel material (plate) through a continuous casting process or a ingot-plate forming process,
    Petition 870180066007, of 7/31/2018, p. 18/37
    12/24 hot rolling the plate using a commonly known method, hot coil annealing if necessary, cold rolling, final annealing or decarburizing annealing under the following condition.
    HOT COIL RECOVERING [0048] Hot coil annealing is carried out to provide the texture of the steel sheet after hot rolling and before cold rolling in a preferable recrystallization structure of regulated and finely divided grains. However, if the hot coil annealing is conducted under conditions of higher temperature and longer time as in conventional techniques, the crystal grains are thickened exceeding 100 μπι and consequently the magnetic flux density in the lamination direction is decreased when heating fast is carried out on the final annealing. In the invention, therefore, when hot coil annealing is conducted, to provide the crystal grain size in no more than 100 μπι, it is preferable to conduct the hot coil annealing at a lower temperature for a shorter time . Concretely, the annealing is preferably conducted under a condition that a saturation temperature is 800 ~ 950Ό and a maintenance time is not more than 60 seconds, more preferably under a condition that a temperature is not lower than 800Ό m more low than 920Ό and the time is no more than 60 seconds. By hot coil annealing, the magnetic flux density and iron loss property after the final annealing can be greatly improved.
    COLD LAMINATION [0049] Likewise, the subsequent cold lamination can be a single cold lamination or two or more cold laminations with an intermediate annealing between them. Also, the reduction of lamination
    Petition 870180066007, of 7/31/2018, p. 19/37
    Cold 13/24 is not particularly limited as long as the condition is the same as in the ordinary production of unoriented electric steel sheet.
    FINAL Annealing [0050] In the final annealing after cold rolling (recrystallization annealing), it is necessary to conduct rapid heating at an average temperature rise rate of not less than 100o / s to a temperature exceeding the recrystallization temperature. In addition, a final temperature in rapid heating is preferable to be higher to cause recrystallization in a short time, but if it exceeds 850Ό, the equipment load required for heating becomes very large and the equipment cost becomes increased . Therefore, the final temperature in the rapid heating is preferably not higher than 850Ό, more preferably not higher than 740Ό.
    [0051] After rapid heating up to a temperature exceeding the recrystallization temperature, the sheet is further heated to a saturation temperature, but its rate of temperature rise is not particularly limited. It is preferable that the saturation temperature is 850-1100 “C and the maintenance time is 5-60 seconds. When the saturation temperature is lower than 850Ό or the maintenance time is less than 5 seconds, the grain growth does not proceed, while when the saturation temperature exceeds 1100Ό or the maintenance time exceeds 60 seconds, the load in the annealing equipment it becomes big. As a more preferable saturation condition, it is desired to keep the plate at a temperature of 900-1050Ό for 10-40 seconds.
    [0052] Furthermore, the method of making the rate of temperature rise not less than 10000 / s is not particularly limited because a direct current heating method or a method
    Petition 870180066007, of 7/31/2018, p. 20/37
    14/24 induction heating can be used.
    DECARBURATION RECOVERY [0053] In order to prevent magnetic aging in a product sheet if the C content in the raw material is more than 0.005% by mass, the steel sheet after saturation is preferable to be subsequently subjected to annealing decarburization to reduce the C content to no more than 0.005% by weight, more preferably to no more than 0.003% by weight. In addition, decarburization annealing can be carried out at any time after rapid heating. Also, decarburization can be conducted under commonly known conditions. For example, a condition of 850Ό x 30 s can be exemplified in an oxidizing atmosphere having a dew point of 30Ό.
    [0054] In addition, the cooling condition after saturation or after decarburization annealing is not particularly limited, and may be, for example, a gas cooling of no more than SOO / s.
    [0055] Preferably, the steel sheet after the final annealing can subsequently be subjected to the formation of an insulating coating, if necessary, to provide a product sheet.
    EXAMPLES [0056] Each of the N-1 ~ 34 steels having a chemical composition shown in table 1 is melted to form a plate. Then, the plate is heated to 1080Ό for 30 minutes and hot rolled to form a 2.3 mm thick hot rolled plate. Then, the hot-rolled sheet is subjected to a hot coil annealing of 850-1100Ό x 30 seconds and still a single cold mining to form a cold-rolled sheet having a final thickness of 0.35 mm. Subsequently, the cold-rolled sheet is subjected to final annealing by heating in a
    Petition 870180066007, of 7/31/2018, p. 21/37
    15/24 direct current while varying a rate of temperature rise and a final temperature of rapid heating as shown in table 2, still heating to a saturation temperature at SOO / s, maintaining for 10 seconds and cooling. In addition, when the C content in the crude steel material is not less than 0.005%, the steel sheet is heated to 850Ό, subjected to decongesting annealing of 850Ό x 30 seconds in an atmosphere having a dew point of 30Ό to reduce the C content to no more than 0.0030% by weight, and then heated to saturation temperature. In a portion of the steel sheets, the crystal grain size is changed by varying an annealing time for hot coil annealing.
    Petition 870180066007, of 7/31/2018, p. 22/37
    16/24
    Comments invention invention invention invention Comparative steel Comparative steel Invention steel Comparative steel invention invention invention invention invention Comparative steel Invention steel I Steel I Steel I Steel I Steel I Steel I Steel I Steel I Steel I Steel Chemical composition (% by mass) Sb 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 Sn 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 z 0.0021 0.0020 0.0018 0.0015 0.0017 0.0018 0.0025 0.0015 0.0015 0.0015 0.0028 0.0029 0.0022 0.0021 0.0015 < 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.100 0.500 1,200 2.50 4.50 0.001 ω 0.0012 0.0021 0.0025 0.0014 0.0012 0.0014 0.0018 0.0014 0.0026 0.0014 0.0022 0.0014 0.0014 0.0015 0.0014 Μη 0.15 0.15 0.10 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.15 0.10 0.07 ώ 3.0 3.0 3.0 3.0 3.3 3.3 3.7 ° J LOl 3.0 3.0 3.0 2.0 1.8 2.0 3.0 Ο 0.0025 0.0050 0.010 0.020 0.05 0.10 0.030 0.020 0.015 0.0030 0.0030 0.0030 0.0025 0.0030 0.0025 Steel No. - OJ ηLO CO 1 ^ - 00 O) O - CM COLO
    Petition 870180066007, of 7/31/2018, p. 23/37
    17/24
    Comments Invention steel Invention steel Comparative steel Comparative steel Comparative steel invention invention invention invention invention invention invention invention invention invention I Steel I Steel I Steel I Steel I Steel I Steel I Steel I Steel I Steel I Steel Chemical composition (% by mass) Sb 0.0010 0.0010 0.0010 0.0010 0.0010 0.0010 0.050 0.030 0800Ό 0.0010 0.10 0.0010 0.0010 0.0010 0.0010 Sn 0.0010 0.0010 0.0010 0.0010 0.0010 0.050 0.030 0800Ό 0.0010 0.10 0.0010 0.0010 0.0010 0.0010 0.0010 z 0.0015 0.0017 0.0015 0.0015 0.0080 0.0015 0.0024 0.0015 0.0023 0.0015 0.0022 0.0022 0.0014 0.0024 0.0019 < 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 0.001 ω 0.0016 0.0016 0.0018 0.0090 0.0019 0.0014 0.0024 0.0014 0.0014 0.0028 0.0018 0.0018 0.0017 0.0013 0.0015 Μη 1.0 2.5 51 0.15 0.15 0.15 0.15 0.07 0.15 0.15 0.15 0.15 0.16 0.16 0.15 ώ 2.5 2.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 Ο 0.0025 0.0020 0.0025 0.0025 0.0025 0.0020 0.0020 0.0100 0.0070 0.0200 0.0020 0.0020 0.0025 0.0020 0.0025 Steel No. co 1 ^ - 00 O) 20 CM 22 23 24 25 26 27 28 29 30
    Petition 870180066007, of 7/31/2018, p. 24/37
    18/24
    Comments Invention steel Invention steel Invention steel Invention steel Invention steel Invention steel Invention steel Invention steel O O O O O O O O .Ω O O O O O O O O(/) O O O O O O O O O O O O O O O O O O O O O O O O ç O O O O O O O O(/) O O O O O O O O O O O O O O O O O) O) OO O CXI CM CM CM CM CM .. 2 O O O O O O O O COO O O O O O O O ω COO O O O O O O O COANDE φ O < O O O O O O O OO O O O_ O O O O O' O' O' T— O' O' O' O' COOANDLO LO 1 ^ - O 00 00 LO LO CTT— T— O CM T— T— T— T— Q ω O O O O O O O O tco O O O O O O O O OO O O O O O O O ωOO.ANDOLO LO O LO O O LO LOX— X— LO X— CM CM X— X—O OO O O O O O O O O O LO O OCO CO CO CO CO CO CO LO LO LO LO LO LO O O CN CXI CM CM CM CM CM CMO O O O O O O O OO O O O O O O O O O O O O O O O The ZCXI COLO CO 1 ^ - 00 O o CO CO CO CO CO CO CO CO <
    Petition 870180066007, of 7/31/2018, p. 25/37
    19/24
    Comments Example of the invention Example of the invention Example of the invention Example of the invention Comparative example Example of the invention Example of the invention Comparative example Comparative example Example of the invention Magnetic properties Magnetic flux density Bso-l (T) 1.76 1.74 1.76 1.76 1.73 CO 1 ^ 1.79 1 ^1 ^ Final annealing conditions Saturation temperature(O) 950 950 950 950 950 950 950 850 850 1025 Rapid heating temperature rise rate (fC / s) 150 150 150 150 150 200 200 300 300 300 Fast heating end temperature (fC) 750 750 750 750 750 740 740 00 CO 740 740 Grain size before cold rolling (μπι) 09 25 70 0 CO m | 85 70 65 65 POO Annealing of hot rolled sheet Annealing time(s) 30 none 30 09 06 30 30 30 30 30 Annealing temperatureCC) 0 1 ^ CO 006 006 006 930 006 0 COCO 0 COCO 950 Steel No. - (XI (XI (XI (XI COmi (HI 1 ^ Steel sheetNo. - (XI COm (O 1 ^ CO 05 0
    Petition 870180066007, of 7/31/2018, p. 26/37
    20/24
    Comments Comparative example Example of the invention Example of the invention Example of the invention Example of the invention Example of the invention Comparative example Example of the invention Comparative example Example of the invention Magnetic properties Magnetic flux density Bso-l (T) Break during cold rolling 1.79 1.79 1.75 1.75 1.75 CXI 1.75 Break during cold rolling 1.76 Final annealing conditions Saturation temperature(O) 950 1000 950 950 950 950 006 950 Rapid heating temperature rise rate (fC / s) 120 120 150 150 150 150 200 250 Fast heating end temperature (fC) 730 730 830 820 820 820 0 CO 1 ^ 740 Grain size before cold rolling (μπι) 1 ^ CO72 70 70 0 CO o | 70 06 09 Annealing of hot rolled sheet Annealing time(s) 30 30 30 30 30 09 06 30 30 30 Annealing temperatureCC) 930 006 006 006 006 006 006 006 1000 0 1 ^ CO Steel No. COI 05 0 - CXI CXI CXI CO SISteel sheetNo. - CXI CO CD 1 ^ CO 05 20
    Petition 870180066007, of 7/31/2018, p. 27/37
    21/24
    Comments Example of the invention Example of the invention Comparative example Comparative example Comparative example Example of the invention Example of the invention Example of the invention Example of the invention Example of the invention Magnetic properties Magnetic flux density Bso-l (T) 1 ^1 ^ CO 1 ^ 1.73 1.701 ^1 ^ 1 ^1 ^ CO 1 ^ 1 ^1 ^ 1.79 Final annealing conditions Saturation temperature(O) 950 006 006 1000 1000 1025 1025 1000 1000 1000 Rapid heating temperature rise rate (O / s) 250 250 300 300 300 350 350 350 250 250 Final rapid heating temperature (Ό) 740 740 740 0 CO 1 ^ 0 CO 1 ^ 740 740 730 740 730 Grain size before cold rolling (pm) 70 70 70 1 ^ CO 85 70 70 62 62 CO (O Annealing of hot rolled sheet Annealing time(s) 30 30 30 30 30 30 30 30 30 30 Annealing temperature(O) 006 006 006 950 950 006 006 0 (CO 0 (CO 890 Steel No. (O 1 ^ 2 | 21CM 22 23 24 25 Steel sheetNo. CM 22 23 24 25 26 27 28 29 30
    Petition 870180066007, of 7/31/2018, p. 28/37
    22/24
    Comments Example of the invention Example of the invention Comparative example Comparative example Comparative example Comparative example Comparative example Example of the invention Example of the invention Example of the invention Magnetic properties Magnetic flux density Bso-l (T) 1 ^1 ^ 1 ^1 ^ 1.69 1.70 CXI 1 ^ CXI 1 ^1 ^1 ^ 1.75 1.89 Final annealing conditions Saturation temperature(O) 1025 1025 950 950 1000 1000 1000 950 950 006 Rapid heating temperature rise rate (O / s) 350 350 οε 08 200 200 200 150 300 200 Final rapid heating temperature (Ό) 740 740 810 740 740 0 CO 1 ^ 790 740 750 750 Grain size before cold rolling (μπι) 70 70 70 70 150 180 210 09 70 70 Annealing of hot rolled sheet Annealing time(s) 30 30 30 30 30 30 30 30 30 40 Annealing temperatureCO 006 006 006 006 1030 0 CD 0 1090 0 1 ^ CO 006 006 Steel No. 26 27 28 29 30 CO 32 33 34 35 Steel sheetNo. CO 32 33 34 35 36 37 38 39 40
    Petition 870180066007, of 7/31/2018, p. 29/37
    23/24
    Comments Example of the invention Example of the invention Example of the invention Magnetic properties Magnetic flux density Bso-l (T) 1.88 1 ^ 1 ^ Final annealing conditions Saturation temperatureCC) 006 1000 1000 Rapid heating temperature rise rateCC / s) 250 250 300 Fast heating end temperature (fC) 750 740 740 Grain size before cold rolling (μπι) 0 CO 85 75 Annealing of hot rolled sheet Annealing time(s) 50 40 50 Annealing temperature(O) 920 950 006 Steel No. 36 37 38 Steel sheetNo. 5 42 43
    Petition 870180066007, of 7/31/2018, p. 30/37
    24/24 [0057] From each of the cold-rolled steel sheets thus obtained after final annealing, a sample is cut in the L direction 180 mm long x 30 mm wide, which is subjected to a single plate magnetic test to measure a magnetic flux density in the lamination direction (Bso-l). The measured results are also shown in table 2.
    [0058] As noted in Table 2, the steel sheets of the Examples of the Invention obtained by controlling the crystal grain size before cold rolling to no more than 100 μΐη and making the rate of temperature rise at the final annealing not less than 10000 / s have excellent magnetic properties in which the magnetic flux density in the Bso-1 lamination direction is not less than 1.74 T.
    权利要求:
    Claims (2)
    [1]
    1. Method of producing an electric steel sheet not oriented by hot rolling of a crude steel material, consisting of:
    C: not more than 0.03% by mass,
    Si: no more than 4% by mass,
    Mn: 0.03-3% by mass,
    Al: not more than 0.01% by mass,
    S: no more than 0.005% by mass,
    N: not more than 0.005% by mass, and optionally consisting of;
    one or two of Sn and Sb in an amount of 0.005-0.5% by weight, respectively;
    and the balance being Fe and incidental impurities, hot coil annealing, cold rolling and then final annealing to produce an unoriented electric steel plate, characterized by the fact that a crystal grain size before cold rolling is provided at not more than 100 μπι and the final annealing is carried out by rapidly heating to a temperature exceeding the recrystallization temperature at an average temperature rise rate of not less than 10000 / s.
    [2]
    2. Method of producing a non-oriented electric steel sheet, according to claim 1, characterized by the fact that decarburization annealing is carried out after rapid heating.
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    同族专利:
    公开号 | 公开日
    BR112013015464A2|2016-09-20|
    MX2013006979A|2013-07-29|
    KR20130101092A|2013-09-12|
    EP2657355A1|2013-10-30|
    JP2012132070A|2012-07-12|
    RU2534638C1|2014-12-10|
    TWI490342B|2015-07-01|
    WO2012086534A1|2012-06-28|
    JP5668460B2|2015-02-12|
    CN103270179A|2013-08-28|
    EP2657355B1|2015-12-09|
    MX351017B|2017-09-28|
    CA2821087A1|2012-06-28|
    US20130263981A1|2013-10-10|
    CA2821087C|2016-09-13|
    TW201233813A|2012-08-16|
    KR101508082B1|2015-04-07|
    EP2657355A4|2014-07-09|
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    法律状态:
    2018-05-02| B07A| Technical examination (opinion): publication of technical examination (opinion)|
    2018-09-11| B06A| Notification to applicant to reply to the report for non-patentability or inadequacy of the application according art. 36 industrial patent law|
    2019-01-15| B09A| Decision: intention to grant|
    2019-03-26| B16A| Patent or certificate of addition of invention granted|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 16/12/2011, OBSERVADAS AS CONDICOES LEGAIS. |
    优先权:
    申请号 | 申请日 | 专利标题
    JP2010285335A|JP5668460B2|2010-12-22|2010-12-22|Method for producing non-oriented electrical steel sheet|
    JP2010-285335|2010-12-22|
    PCT/JP2011/079150|WO2012086534A1|2010-12-22|2011-12-16|Process for production of non-oriented electromagnetic steel sheet|
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